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Dresden 2009 – wissenschaftliches Programm

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MA: Fachverband Magnetismus

MA 31: Magnetic Particles and Clusters I

MA 31.6: Vortrag

Donnerstag, 26. März 2009, 11:30–11:45, HSZ 401

Detailed study on oxidation behavior of FePt thin film and nanoparticles — •Luyang Han1, Kuerbanjiang Balati1,2, Ulf Wiedwald1, and Paul Ziemann11Institut für Festkörperphysik, Universität Ulm, A.-Einstein-Allee 11, 89081 Ulm, Germany — 2Institut für Mikro- und Nanomaterial, Universität Ulm

FePt nanoparticles and thin films attract great attention due to their potential application as magnetic data storage media [1]. In this study the oxidation of FePt nanoparticles and an epitaxial FePt reference film are investigated in detail. The nanoparticles are prepared by means of reverse micelles [2]. Oxidation is tracked in detail using X-ray photoelectron spectroscopy and a core-shell model is established to extract the oxide layer thickness. During the oxidation process a layer of Fe2O3 is formed at the surface, while Pt atoms remain metallic. After oxygen exposure of 108 L chemically disordered FePt particles start to oxidize, while the partially ordered particles after in-situ annealing at 950 K show only slight oxidation after 1010 L oxygen exposure. Similar behavior is observed for FePt thin films, indicating that the formation of the chemically ordered L10 structure reduces the oxidation speed significantly.

[1]S. Sun, Adv. Mater., 18, 393, (2006)

[2]A. Ethirajan et al., Adv. Mater., 19, 406, (2007)

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