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Berlin 2012 – scientific programme

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KR: Fachgruppe Kristallographie

KR 5: Poster I – including Multiferroics (MA with DF, DS, KR, TT)

KR 5.41: Poster

Tuesday, March 27, 2012, 12:15–15:15, Poster A

Chemical solution deposition of multiferroic La0.7Sr0.3MnO3, BaTiO3 thin films prepared by ink plotting — •Anke Kirchner1, Melis Arin2, Petra Lommens2, Xavier Granados3, Susagna Ricart3, Bernhard Holzapfel1, and Isabel van Driessche21IFW Dresden, Institute for Metallic Materials, Helmholtzstr. 20, 01069 Dresden, Germany — 2SCRiPTs, Department of Inorganic and Physical Chemistry, Ghent University, Krijgslaan 281 (S3), 9000 Ghent, Belgium — 3Materials Science Institute of Barcelona, CSIC-ICMAB, Campus Universitat Autònoma de Barcelona, 08193 Bellaterra, Spain

Ferroelectric BaTiO3 (BTO) as well as ferromagnetic La0.7SrMnO (LSMO) thin films were prepared by chemical solution deposition (CSD). Based on these, a multiferroic architecture stack of La0.7Sr0.3MnO3 / BaTiO3 layers was developed. Aqueous, environmentally friendly precursor solutions were formulated for both materials. These are used for ink plotting on SrTiO3 (100) substrates. Films were subjected to a subsequent thermal treatment at the corresponding crystallization temperature. The structural as well as the magnetic and electric properties are presented. The Curie temperature of the ferromagnetic LSMO layer with a film thickness of only 60 nm was determined to 360 K. The magnetization curve indicates a hysteresis loop with a saturation magnetization above 400 emu/cm3. The ferroelectric character of the BTO films was demonstrated by polarization curves.

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