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Dresden 2014 – scientific programme

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DF: Fachverband Dielektrische Festkörper

DF 8: Multiferroics I (Joint Session with MA, DS, KR, TT)

DF 8.7: Talk

Tuesday, April 1, 2014, 11:15–11:30, BEY 118

Investigation of A-site Bismuth based double perovskites as potential room-temperature multiferroics — •Vikas Shabadi, Mehran VafaeeKhanjani, Mehrdad BaghaieYazdi, Aldin Radetinac, Philipp Komissinskiy, and Lambert Alff — Institute of Materials Science, Technische Universität Darmstadt, Germany

A-site Bismuth based double perovskites (Bi2BB’O6), where ferroelectricity arises from the stereochemically active 6s2 lone pair of electrons on the Bi3+ cations, provide a vital test bed to engineer room temperature multiferroicity. Here, different combinations of 3d-3d or 3d-5d cations may be introduced at the B-site in order to obtain an effective ferri/ferromagnetic moment. The 3d-3d compound Bi2FeCrO6 (BFCO) has drawn a heightened interest due to its large experimentally reported ferroelectricity and divergent observations of its magnetic properties. We report epitaxial BFCO thin films grown by pulsed laser deposition on single crystal SrTiO3(100) substrates. Detailed structural characterization was performed by X-ray Diffraction and the magnetic properties were studied with a SQUID magnetometer. We show that BFCO adopts a superstructure with the same unit cell as the chemically ordered double perovskite. The magnetization is a function of chemical but not of structural order.

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