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Dresden 2017 – scientific programme

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HL: Fachverband Halbleiterphysik

HL 64: Poster: Photovoltaics and Optics

HL 64.32: Poster

Wednesday, March 22, 2017, 15:00–19:00, P1C

Time resolved photoluminescence of Cu2ZnSn(S,Se)4 solar cell absorbers with varying compositionMario Lang1, Tobias Renz1, Niklas Mathes1, Markus Neuwirth1, Thomas Schnabel2, •André Schendel1, Heinz Kalt1, and Michael Hetterich1,31Institute of Applied Physics, Karlsruhe Institute of Technology (KIT), 76131 Karlsruhe, Germany — 2Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg, 70565 Stuttgart, Germany — 3Light Technology Institute, KIT, 76131 Karlsruhe, Germany

Cu2ZnSn(S,Se)4 absorbers offer a huge potential for future thin-film solar cells. Up to now the low efficiency is predominantly caused by the low open circuit voltage VOC compared to the theoretical possible VOC. The reasons for the low open-circuit voltage are amongst others miscellaneous defects and secondary phases within the material. To suppress their formation absorber layers with off-stoichiometric Cu poor and Zn rich composition are used for highly efficient devices. In our contribution we analyze the effect of the composition on the radiative recombination by means of photoluminescence (PL) and especially time-resolved photoluminescence (TRPL).

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