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CPP: Fachverband Chemische Physik und Polymerphysik
CPP 17: Poster I
CPP 17.30: Poster
Montag, 9. März 2026, 19:00–21:00, P5
High-Power Continuous Laser-Guided Synthesis of Bimetallic Metal-Organic Framework (NiCoMOF) Structures and Their Composites: Photophysical, Photochemical, and Electrical Characterization — •Saliha MUTLU1,2, Bülend ORTAÇ2, Ali KARATUTLU2,3, Nergis ARSU4, and Sevil SAVAŞKAN YILMAZ1,2 — 1Karadeniz Technical University Chemistry Department, Trabzon, Türkiye — 2Bilkent University, Institute of Materials Science Nanotechnology and National Nanotechnology Research Center (UNAM), Ankara, 06800 Turkey — 3Sivas University of Science and Technology, Department of Engineering Basic Sciences, Sivas, 58100 Turkey — 4Department of Chemistry, Yildiz Technical University, Davutpasa Campus, Istanbul 34210, Turkey;
Metal-organic frameworks (MOFs) are among the most innovative breakthroughs in chemistry and materials science. In this study, the first bimetallic synthesis of MOFs was achieved using the high-power laser-induced rapid synthesis (LIRS) method via two different ligand and metal salt combinations with different π-conjugated linkers. The synthesis of NiCo-MOF structures (in 1:2 and 2:1 ratios) was completed in just 70 minutes using the LIRS method. Furthermore, the synthesis of MOF composites (rGO/MOF) containing reduced graphene oxide (rGO) was also achieved for the first time. On top of these, the electrical properties of the epoxy acrylate-based MOF and rGO@MOF composites prepared by in situ photopolymerization were investigated in detail. This study was supported by TÜBITAK-BIDEB 2211-A National PhD Scholarship Programs.
Keywords: Laser-induced rapid synthesis; metal-organic frameworks; energy storage; polymer composite; in-situ polymerization