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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 56: Molecular and Polymer Dynamics, Friction and Rheology I

CPP 56.1: Invited Talk

Friday, March 13, 2026, 10:45–11:15, HÜL/S386

Liquid Dynamics at Interfaces — •Michael Vogel — Institut für Physik kondensierter Materie, TU Darmstadt, Hochschulstraße 6, 64289 Darmstadt

Liquids at interfaces are of great importance in nature and technology, for instance, in biological cells, clay minerals, and energy materials. Typically, the dynamics of liquids at interfaces significantly differ from those in the bulk. We combine nuclear magnetic resonance and broadband dielectric spectroscopy with molecular dynamics simulutations to determine the magnitude and range of these interface effects in broad frequency and temperature ranges. It is shown that the free energy landscape imposed by an interface on an adjoining liquid enables a basic understanding of the altered dynamical behavior [1]. It will be discussed that a knowledge of interface effects allows one not only to obtain valuable insights into the properties of confined water and, when avoiding crystallization, the anomalies and vitrification of bulk water [2-4], but also to steer ion transport in electrolyte-host systems for improved lithium-ion battery and proton-exchange membrane materials [5-7].

[1] S. Hefner et al., Phys. Rev. Lett. 133, 106201 (2024)

[2] V. Schiller and M. Vogel, Phys. Rev. Lett. 132, 016201 (2024)

[3] J. H. Melillo et al., PNAS 121, e2407030121 (2024)

[4] E. Steinrücken et al., J. Phys. Chem. Lett. 14, 4104 (2023)

[5] M. Stevenson et al., Adv. Funct. Mater. e15706 (2025)

[6] S. F. Winterstein et al., J. Am. Chem. Soc. 145, 27563 (2023)

[7] A. F. Privalov et al., J. Phys. Chem. Lett. 14, 9335 (2023)

Keywords: Complex Liquids; Interfaces; Water; NMR Spectroscopy; Molecular Dynamics Simulations

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