DPG Phi
Verhandlungen
Verhandlungen
DPG

München 2004 – wissenschaftliches Programm

Bereiche | Tage | Auswahl | Suche | Downloads | Hilfe

MO: Molekülphysik

MO 3: Elektronische Überg
änge

MO 3.8: Vortrag

Montag, 22. März 2004, 12:45–13:00, HS 355

Spectroscopy of the XeC2 molecule in Xenon, Argon and Krypton matrices — •Marcin Frankowski, Alice M. Smith-Gicklhorn, and Vladimir E. Bondybey — Institut für Physikalische und Theoretische Chemie, Technische Universität München, Lichtenbergstr. 4, 85748, Garching, Germany

A self-igniting DC-electric discharge of C2H2 in Xe (matrix gas) or C2H2/Xe in Ar or Kr (matrix gases) is used to produce and study the XeC2 molecule in these various rare gases at 12 K. Unlike in Ar and Kr matrices, the well-known electronic spectra of C2 is completely absent in a Xe matrix. This together with annealing experiments in Ar matrices indicate that ground state Xe and C2 react uniquely and without a barrier to form the XeC2 molecule. The infrared-active C-C stretch of this compound is found to be close to the C-C stretching frequency of C2 anion, in excellent agreement with our density functional theoretical (DFT) calculations which yield a XeCC singlet species bent by 148.6o and with substantial charge separation approaching Xe+C2 and a notably short, 2.107 Å, Xe-C bond. The spectra of the Xe-13C-12C, Xe-12C-13C and Xe-13C-13C species are also obtained and the isotopic shifts are in excellent agreement with the DFT predictions, although not sufficient to distinguish a bent from a linear structure.

Numerous broad absorptions centered near 423 nm (in Xe) are observed which are clearly due to the XeC2 molecule. Laser-induced fluorescence studies reveal a near-infrared emission likely due to XeC2 but not yet understood.

100% | Mobil-Ansicht | English Version | Kontakt/Impressum/Datenschutz
DPG-Physik > DPG-Verhandlungen > 2004 > München