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Regensburg 2004 – wissenschaftliches Programm

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HL: Halbleiterphysik

HL 12: Poster I

HL 12.70: Poster

Montag, 8. März 2004, 16:30–19:00, Poster A

Energy transfer from band states into the Mn 3d5 shell of (Zn,Mn)S nanowires — •J. Kampmann1, L. Chen1, P.J. Klar1, W. Heimbrodt1, F.J. Brieler2, and M. Fröba21FB Physik und WZMW, Philipps-Universität, Marburg — 2Institut für Anorganische and Analytische Chemie, Justus-Liebig Universität, Gießen

The energy transfer from the band states into the Mn 3d5 shell in (II,Mn)VI wide-gap diluted magnetic semiconductors is a well known feature of the bulk compounds. As a result the luminescence properties of these materials are dominated by the yellow luminescence band of the lowest transition in the Mn 3d5 shell between the 4T1 (S=3/2) first excited state to the 6A1 (S=5/2) ground state. The energy transfer between the two subsystems, extended band states and Mn 3d5 shell, is a Dexter-Förster like process. The mechanisms for overcoming the violation of the spin selection rule Δ S=0 are still under debate. We present first studies of the luminescence and transfer dynamics of the yellow Mn-luminescence in Zn1−xMnxS nanowires with diameters ranging from 3 to 9 nm and x between 0.01 and 0.3.

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