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Regensburg 2010 – scientific programme

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 20: Organic Electronics and Photovoltaics II

CPP 20.5: Talk

Tuesday, March 23, 2010, 14:45–15:00, H37

Study of Sub-Bandgap States in Polymer-Fullerene Solar Cells — •Martin Presselt1, Felix Herrmann1, Marco Seeland1, Maik Bärenklau1, Sebastian Engmann1, Roland Rösch1, Wichard J. D. Beenken2, Sviatoslav Shokhovets1, Harald Hoppe1, and Gerhard Gobsch11Experimental Physics I, Institute of Physics & Institute of Micro- und Nanotechnologies, Ilmenau University of Technology, Weimarer Str. 32, 98693 Ilmenau, Germany — 2Theoretical Physics I, Institute of Physics, Ilmenau University of Technology, Weimarer Str. 25, 98693 Ilmenau, Germany

At present polymer-fullerene blends are widely used to build organic solar cells. The main contribution to their photocurrent originates from optical transitions between occupied states below the HOMO level and unoccupied states above the LUMO level of the polymer.

In this work, we investigated the origin of states contributing to the optical absorption in the sub-bandgap spectral range and the resulting photocurrent in P3HT-PCBM bulk heterojunction solar cells. Photothermal deflection spectroscopy, temperature dependent external quantum efficiency, photoluminescence and electroluminescence as well as spectroscopic ellipsometry measurements have been carried out. Effects due to different P3HT-PCBM blending ratios and annealing temperatures have been studied.

Two models are discussed to explain the experimental observations: optical transitions involving (a) disorder and/or defect related states, and (b) charge transfer complexes.

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