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Regensburg 2010 – scientific programme

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 26: Micro and Nanofluidics I

CPP 26.2: Talk

Wednesday, March 24, 2010, 14:15–14:30, H39

Pore-scale investigations of multiphase fluid systems subject to freeze-thaw — •Kamaljit Singh1, 2, 3, Robert K. Niven1, Timothy J. Senden4, Michael L. Turner4, Adrian P. Sheppard4, Jill P. Middleton4, and Mark A. Knackstedt41School of Aerospace, Civil and Mechanical Engineering, The University of New South Wales at ADFA, Northcott Drive, Canberra, ACT, 2600, Australia — 2Max Planck Institute for Dynamics and Self-Organization, D-37018 Göttingen, Germany — 3Experimental Physics, Saarland University, 66123 Saarbrücken, Germany — 4Department of Applied Mathematics, Research School of Physics and Engineering, Australian National University, ACT, 0200, Australia

The pore scale behavior of non-aqueous phase liquid (NAPL) contaminants in porous media undergoing freeze-thaw cycles is studied by conducting various experiments, including two-dimensional micromodels, containing residual NAPL in a monolayer of glass beads; and three-dimensional glass-bead cell using X-ray micro-computed tomography. It is shown that freeze-thaw cycles have a substantial impact on the distribution of residual NAPL (in initially water saturated porous media), including the rupture and remobilization of trapped NAPL due to freezing-induced pressure forces, and ganglion fragmentation into singlet ganglia. The results of these experiments are interpreted by developing pore-scale models. The findings have important implications for the behavior of subsurface NAPL contamination in cold climate regions.

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