Dresden 2014 – wissenschaftliches Programm
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CPP: Fachverband Chemische Physik und Polymerphysik
CPP 52: Biomaterials and Biopolymers (joint session with BP) II
CPP 52.12: Vortrag
Donnerstag, 3. April 2014, 18:15–18:30, ZEU 222
Dynamic glass transition in room temperature ionic liquids with calorimetric methods. — •Evgeni Shoifet1,2, Heiko Huth1, Sergey Verevkin2,3, and Christoph Schick1,2 — 1Institute of Physics, Rostock University, Rostock, 18051, Germany — 2Interdisciplinary Faculty, Rostock University, Rostock, 18051, Germany — 3Institute of Chemistry, Rostock University, Rostock, 18051, Germany
Many ionic liquids are good glass formers. Nevertheless, only a few studies of the glass transition in ionic liquids are available so far. Particularly the frequency dependence of the dynamic glass transition (α-relaxation) is not known for most ionic liquids. The standard technique for such studies - dielectric spectroscopy - is not easily applicable to ionic liquids because of the high electrical conductivity. We try to use calorimetric techniques to obtain complex heat capacity and to investigate the dynamic glass transition of room temperature ionic liquids (RTILs) in a wide frequency range. This can give an insight in cooperative motions of ions and ion clusters in RTILs.