Dresden 2014 – wissenschaftliches Programm

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O: Fachverband Oberflächenphysik

O 54: Organic Electronics and Photovoltaics V (CPP jointly with DS, HL, O)

O 54.10: Vortrag

Mittwoch, 2. April 2014, 17:30–17:45, ZEU 260

Optical studies of excitonic precursor spin species under magnetic resonance in organic light emitting diodes. — •Hermann Kraus, Sebastian Bange, and John M. Lupton — Universität Regensburg, 93040 Regensburg, Deutschland

Large magnetoresistance effects e.g. due to spin-dependent recombination rates are well-known for OLEDs [C. Boehme et al., Nat. Nano 8, 612 (2013)], although models are still under debate given that they remain hard to verify from a measurement of integrated current and luminance values[J. M. Lupton et al., Nature Mat. 7, 598 (2008)]. Spin resonance of paramagnetic species enables direct manipulation of carrier and excitonic precursor spins, providing a wealth of new insight into dynamic spin properties. Previous work on electrical or optical detection of spin manipulation [W. J. Baker et al., Nature Comm. 3, 898 (2012); W. J. Baker et al., Phys. Rev. B 84, 165205 (2011)] misses out on the opportunity to directly observe the presence of triplet exciton species that are at the heart of spin-dependent recombination models. A few polymeric and small-molecular compounds are now known to exhibit reasonable triplet emission without modification of the polaron pair and exciton dynamics by strong spin-orbit interaction [D. Chaudhuri et al., Angew. Chem. Int. Ed. DOI 10.1002/anie.201307601(2013); J. M. Lupton et al., Phys. Rev. Lett. 89 167401(2002)]. Those materials are ideal candidates to directly track spin singlet and triplet excitonic species in organic light-emitting diodes under conditions of magnetic resonance, by comparing the fluorescence (singlet) to phosphorescence (triplet) intensity.