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HL: Fachverband Halbleiterphysik

HL 30: Photovoltaics: Nanostructured materials

HL 30.4: Talk

Tuesday, March 17, 2015, 11:00–11:15, ER 164

Enhanced photoelectrochemical activity of vertically aligned ZnO-coated TiO2 nanotubes — •Hua Cai^1,2, Qin Yang², Zhigao Hu³, Zhihua Duan³, Qinghu You², Jian Sun², and Jiada Wu² — ¹Helmholtz-Zentrum Dresden-Rossendorf, Dresden, Germany — ²Fudan University, Shanghai, China — ³East China Normal University, Shanghai, China

Vertically aligned ZnO-TiO2 hetero-nanostructures constructed of anatase TiO2 nanotubes (NTs) and wurtzite ZnO coatings are fabricated by atomic layer deposition of ZnO coatings on electrochemical anodization formed TiO2 NTs, and their photoelectrochemical activities are studied through photoelectrochemical and electrochemical characterization. Compared with bare TiO2 NTs, the transient photocurrent increases to over 1.5-fold for the annealed ZnO-coated TiO2 NTs under visible illumination. The ZnO-coated TiO2 NTs also show a longer electron lifetime, a lower charge-transfer resistance and a more negative flat-band potential than the bare TiO2 NTs, confirming the improved photoelectrochemical activity due to the enhanced charge separation.