Heidelberg 2015 – wissenschaftliches Programm

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MO: Fachverband Molekülphysik

MO 5: Posters 1: Novelties in Molecular Physics

MO 5.5: Poster

Montag, 23. März 2015, 17:00–19:00, C/Foyer

Extended quantum jump description of vibronic two-dimensional spectroscopy — •Julian Albert, Martin Kess, Mirjam Falge, Johannes G. Wehner, and Volker Engel — Institut für Physikalische und Theoretische Chemie, Emil-Fischer-Str. 42, Universität Würzburg, 97074 Würzburg, Germany

We calculated two-dimensional vibronic spectra for model systems involving two electronic molecular states. The coupling to a bath is simulated using a quantum-jump approach. For the latter, we use a method introduced by Makarov and Metiu [1] which includes an explicit treatment of dephasing. In this way it is possible to characterize the influence of dissipation and dephasing on the 2D-spectra.

[1] D. E. Makarov and H. Metiu, J. Chem. Phys. 111, 10126 (1999).