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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 53: Biomaterials and Biopolymers II (joint session BP/CPP/MM, organized by MM)

CPP 53.3: Talk

Thursday, March 10, 2016, 12:15–12:30, H52

Fractional dynamics in silk — •Igor Krasnov¹, Tilo Seydel³, and Martin Müller² — ¹IEAP, Universität Kiel, Germany — ²Institute of Materials Research, HZG, Germany — ³ILL, Grenoble, France

Structural relaxations in humid silk fibers exposed to tensile stress have been observed to take place on a very wide range of time scales from a few milliseconds to several hours. The time-dependence of the measured tensile force following a quasi-instantaneously applied external strain on the fibers can be understood in terms of a fractional viscoelastic relaxation function introducing memory effects by which the mechanical state of a fiber depends on its tensile history. [1] An analog fractional relaxation also gives rise to the subdiffusion observed on picosecond time scales, which governs the mobility of the amorphous polymer chains and adsorbed water on the molecular level. The reduction of the subdiffusive memory effect in stretched fibers compared to native fibers is consistent with the higher order of the polymers in the stretched state.

[1] I. Krasnov, T. Seydel, and M. Müller, Phys. Rev. E 91, 042716 (2015)