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Regensburg 2016 – wissenschaftliches Programm

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HL: Fachverband Halbleiterphysik

HL 46: Organic Semiconductors

HL 46.4: Vortrag

Mittwoch, 9. März 2016, 10:45–11:00, H13

α,ω-Dihexyl-sexithiophene thin films for solution-gated organic field-effect transistors — •Hannah Schamoni1, Simon Noever2, Bert Nickel2, Max Kraut1, Martin Stutzmann1, and Jose A. Garrido31Walter Schottky Institut und Physik-Department, Technische Universität München, Deutschland — 2Fakultät für Physik und CeNS, Ludwig-Maximilians-Universität München, Deutschland — 3Catalan Institute of Nanoscience and Nanotechnology, CSIC and The Barcelona Institute of Science and Technology, Barcelona, Spain

While organic semiconductors are being widely investigated for chemical and biochemical sensing applications, major drawbacks such as the poor device stability and low charge carrier mobility in aqueous electrolytes have not yet been solved to complete satisfaction. In this work, solution-gated organic field-effect transistors (SGOFETs) based on the molecule α,ω-dihexyl-sexithiophene are presented as a promising platform for in-electrolyte sensing. It is shown that the performance of the SGOFETs can be improved by choosing suitable growth parameters which lead to a two-dimensional film morphology and a high degree of structural order. Furthermore, the capability of the SGOFETs to detect changes in the pH or ionic strength of the gate electrolyte is demonstrated and successfully simulated. Excellent transistor stability is confirmed by continuously operating the device over a period of several days. Altogether, our results demonstrate the feasibility of high performance and highly stable organic semiconductor devices for chemical or biochemical applications.

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