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Dresden 2017 – wissenschaftliches Programm

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O: Fachverband Oberflächenphysik

O 63: Focus Session: Charge Transport at Surfaces and Nanostructures with Multi-probe Techniques

O 63.14: Poster

Dienstag, 21. März 2017, 18:30–20:30, P2-OG3

Conformation manipulation of binaphthyl-dimer with a low temperature STM — •We-Hyo Soe1, Marek Kolmer2, Xavier Bouju1, Yasuhiro Shirai3, Kosuke Minami3, Katsuhiko Ariga3, and Waka Nakanishi31GNS & MANA Satellite, CEMES, CNRS, Toulouse, France — 2Centre for Nanometer-Scale Science and Advanced Materials (NANOSAM), Jagiellonian University, Krakow, Poland — 3International Center for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), Tsukuba, Ibaraki, Japan

One of the low temperature ultrahigh vacuum scanning tunneling microscope (STM) of the LT-UHV 4-STM has been used to study binaphthyl-dimer molecules on Au(111) [1],[2]. The molecule has three C2 symmetry conformations energetically possible, namely, cis, trans, and planar-like conformations. Right after the molecules deposition on a clean gold surface, only cis conformation molecules forming small 2D islands have been observed. Using a STM tip single molecule mechanical manipulation protocol, single planar conformation molecules have been produced one by one corresponding to our registered nano-car. This confirms that on an Au(111) surface, single and isolated binaphthyl-dimer molecules equipped with 2 paddles are ready to compete for the first international nano-car race in Toulouse, spring 2017.

[1] Y. Shirai, K. Minami, W. Nakanishi, Y. Yonamine, C. Joachim and K. Ariga, Jap. Journ. Appl. Phys., 55 (2016) 1102A2. [2] S. Fujiyoshi, S. Takeuchi, T. Tahara, J. Phys. Chem. A, 108 (2004) 5938.

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