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Berlin 2018 – wissenschaftliches Programm

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MM: Fachverband Metall- und Materialphysik

MM 16: Topical session (Symposium MM): Hydrogen in Materials

MM 16.2: Vortrag

Montag, 12. März 2018, 18:00–18:15, H 0107

Understanding the effect of nanostructured additives on hydride systems by means of electron transmission microscopy — •Julián Puszkiel1,2, María Victoria Castro Riglos3, Caludio Pistidda1, Hujun Cao1, Thi-Thu Le1, Antonio Santoru1, Thomas Klassen1,4, and Martin Dornheim11Helmholtz Zentrum Geesthacht (HZG), Department of Nanotechnology, Geesthacht, Germany. — 2Department of Physicochemistry of Materials, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) and Centro Atómico Bariloche, S.C. de Bariloche, Argentina — 3Department of Metalphysics, Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) and Centro Atómico Bariloche, S.C. de Bariloche, Argentina — 4Helmut Schmidt University, Hamburg, Germany

One of the main limitations for the implementation of hydrogen as energy carrier is the lack of an efficient and safe hydrogen storage system. Hydrogen storage in solid state through the formation of hydride compounds is a potential alternative to address this problem. In recent years, much effort has been devoted to improve the kinetic behavior of promising Li-Mg-B-H and Li-Mg-B-N-H destabilized hydride systems. In this work, nanosized additives added to 2LiBH4+MgH2 and 6Mg(NH2)2+9LiH+ LiBH4 are characterized via transmission electron microscopy (TEM). The aim is to understand the role of in situ formed nanostructured additives on the kinetic behavior of the investigated hydride systems. The information gained by TEM is helpful to optimize solid state hydrogen storage system for practical applications.

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