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CPP: Fachverband Chemische Physik und Polymerphysik
CPP 8: Interfaces and Thin Films (joint session CPP/DY)
CPP 8.6: Vortrag
Montag, 1. April 2019, 16:30–16:45, H14
In-situ GISAXS during sputter deposition of metal nanolayers on functional polymer thin films for lithium-ion batteries — •Simon J. Schaper1, Volker Körstgens1, Matthias Schwartzkopf2, Pallavi Pandit2, Alexander Hinz3, Oleksandr Polonskyi3, Thomas Strunskus3, Franz Faupel3, Stephan V. Roth4, and Peter Müller-Buschbaum1 — 1TU München, Physik-Department, LS Funktionelle Materialien, 85748 Garching — 2DESY, 22607 Hamburg — 3CAU zu Kiel, Institut für Materialwissenschaft, LS Materialverbunde, 24143 Kiel — 4KTH, Department of Fibre and Polymer Technology, SE-100 44 Stockholm, Sweden
Understanding the interface between metals, commonly used as current collectors, and ion-conducting polymers used in polymer lithium-ion batteries (LIBs) is crucial to develop highly reproducible, low-cost and reliable devices. To address these issues, sputter deposition is the technique of choice to fabricate scalable, reproducible and controllable nanometer and sub-nanometer metal layers on polymer thin films. The sputter deposition process, being well understood and controlled, offers advantages over chemical methods to tailor metal thin-flim morphologies on the nanoscale and offers a superior adhesion of the deposited material. We use in-situ grazing incidence small angle X-ray scattering (GISAXS) to investigate the formation, growth and, self-assembled structuring on polymer thin films and composites used in LIBs. Different polymer films are compared with respect to the metal layer growth.