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SAMOP 2021 – wissenschaftliches Programm

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MO: Fachverband Molekülphysik

MO 7: Poster 1

MO 7.22: Poster

Donnerstag, 23. September 2021, 17:30–19:30, P

Mid-IR Photo-induced Dissociation of Solvated (Bio)Molecular Complexes — •Mukhtar Singh1,2,3, Matthew Scott Robinson1,2,3, Hubertus Bromberger1,2, Sebastian Trippel1,2, and Jochen Küpper1,2,31Center for Free-Electron Laser Science, Deutsches Elektronen-Synchrotron DESY, Hamburg — 2Center for Ultrafast Imaging, Universität Hamburg — 3Department of Physics, Universität Hamburg

We present the ultrafast imaging of thermal-energy chemical dynamics of micro-solvated (bio)molecular complexes when probing with strong-field techniques. We produce a pure sample of the molecule of interest in the gas phase by using a combination of a molecular beam and electrostatic deflector [1]. To study the thermally-induced dynamics, we set up a mid-IR pump-probe experiment, in which a 3 µm beam was used to excite the system and then a 1.3 µm nm beam was used for ionising the system. First experiments focus on the ion-imaging of the mid-IR pumped system. Future experiments will use laser-induced electron diffraction (LIED) [2,3] to probe the thermally-induced dynamics and obtain structural information about the system with atomic resolution.

[1] S. Trippel, et al., Rev. Sci. Instrum. 89, 096110 (2018).

[2] J. Wiese, et al., Phys. Rev. Research 3, 013089 (2021).

[3] E. T. Karamatskos, et al., J. Chem. Phys. 150, 244301(2019).

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