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Dresden 2026 – wissenschaftliches Programm

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 17: Poster I

CPP 17.42: Poster

Montag, 9. März 2026, 19:00–21:00, P5

In Situ Investigation of Ag Sputter Deposition on a Zwitterionic Polymer Film — •Georgios Panagiotidis1, Christoph Lindenmeir1, Grace Leone2, Lixing Li1, Lyuyang Cheng1, Doan Le1, Yufeng Zhai3, Kristian Reck4, Benedikt Sochor3, Matthias Schwartzkorpf3, Anurag Keloth5, Sarathlal Vayalil3,5, Todd Emrick2, Thomas Russell2,6, Stephan V. Roth3,7, and Peter Müller-Buschbaum11TUM School of Natural Sciences, Chair for Functional Materials, Garching, Germany — 2UMass Amherst, Massachusetts, United States — 3DESY, Hamburg — 4CAU, Kiel, Germany — 5UPES, Dehradun, India — 6LBNL, Berkeley — 7KTH, Stockholm, Sweden

While organic electronic devices mainly use organic or organic-inorganic hybrid materials, many electrodes still rely on pure metals due to their unparalleled electrical conductivity. Thus, the polymer-metal interface is crucial to device performance. Studies have demonstrated the use of ultrathin metal electrodes for (semi)transparent organic solar cells, and the quality of the interface influences the formation of structural defects, which can increase resistance and the likelihood of a short circuit. These metal contacts are typically deposited through lab-scale methods such as thermal evaporation, while industrial manufacturing prefers large-scale sputter deposition. Moreover, zwitterionic polymers can reduce the work function of metals and serve as interlayers in inverted organic solar cells. Therefore, understanding the growth behavior of sputtered silver on zwitterionic polymer surfaces is critical.

Keywords: GISAXS; Zwitterion; OPV; Sputtering; Silver

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