Dresden 2026 – wissenschaftliches Programm
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FM: Fachverband Funktionsmaterialien
FM 8: Multiferroics and Magnetoelectric Coupling (joint session MA/FM)
FM 8.3: Vortrag
Dienstag, 10. März 2026, 10:00–10:15, POT/0112
Magnetoelectric coupling in antiferromagnetic BiCoO3 — •Veronica Goian1, Fedir Borodavka1, Petr Proschek2, Maxim Savinov1, Christelle Kadlec1, Hong Dong Nguyen1, Andrei A. Belik3, and Stanislav Kamba1 — 1Institute of Physics of the Czech Academy of Sciences, Prague, Czech Republic — 2Department of Condensed Matter Physics, Charles University, Prague Czech Republic — 3National Institute for Materials Science: Tsukuba, Ibaraki, Japan
BiCoO3 is a potential multiferroic material with a C-type antiferromagnetic phase transition at TN=470 K and a hypothetical ferroelectric phase transition around 1000 K (the sample decomposes at around 470 ∘C).[1] First-principles calculations predict an unusually strong antimagnetoelectric coupling in BiCoO3.[2] However, no experimental measurements have been reported in the literature to determine the magnetoelectric coupling or related structural properties. This is mainly because BiCoO3 requires high-pressure and high-temperature sintering. We have measured the dielectric permittivity, ferroelectric hysteresis loops, and Raman, THz, and IR spectra to probe the ferroelectric behavior. In addition, we found that BiCoO3 exhibits well-measurable non-linear magnetoelectric coupling.
[1] Oka et al., J. Am. Chem. Soc., 132, 9438-9443 (2010)
[2] Braun et al., Phys. Rev. B, 110, 144442(2024)
Keywords: magnetoelectric coupling; antiferromagnetism; multiferroic; phonon; ferroelectricity
