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Mainz 2026 – wissenschaftliches Programm

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MO: Fachverband Molekülphysik

MO 24: Molecular Spectroscopy I

MO 24.5: Vortrag

Donnerstag, 5. März 2026, 12:15–12:30, P 204

Orbital-Resolved Bond-Breaking Asymmetry in the Strong-Field Dissociative Double Ionization Channel (N2+ + O+) of N2O — •Feras Afaneh — Physics Department, Faculty of Science, Hashemite University, P.O.Box 330127, Zarqa 13133, JORDAN

The dissociative double ionization of nitrous oxide (N2O), induced by short-pulse polarized laser fields, was investigated using the COLTRIMS technique. Focusing on the dissociative channel (N2+ + O+), we extracted both the molecular-frame photoelectron angular distributions and the ion sum-momentum distributions. Orientation-dependent ionization rates, analyzed across distinct kinetic energy release (KER) regimes, revealed contributions from multiple molecular orbitals. These results reveal a pronounced asymmetry in bond breaking relative to the instantaneous laser field vector, arising from the interplay between orbital geometry and electron localization-assisted enhanced ionization in stretched molecular configurations under strong-field conditions.

Keywords: molecular dissociation; orbital-resolved ionization; photoelectron angular distribution; nitrous oxide; COLTRIMS technique

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