Regensburg 2010 – wissenschaftliches Programm
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CPP: Fachverband Chemische Physik und Polymerphysik
CPP 43: Colloids and Complex Liquids II
CPP 43.14: Vortrag
Donnerstag, 25. März 2010, 17:30–17:45, H39
Is there a Relationship between the Elongational Viscosity and the First Normal Stress Difference in Polymer Solutions? — •Stephan Gier1, Andreas Zell1, Salima Rafai2, and Christian Wagner1 — 1Universität des Saarlandes, Saarbrücken — 2Laboratoire de Spectrometrie Physique, Grenoble
We investigate polymer solutions in shear and elongational flow. Shear flow is created in a cone-plate-geometry of a commercial rheometer. The capillary thinning of a filament of polymer solution in the Capillary Breakup Extensional Rheometer (CaBER) serves as an elongational flow. We compare the relaxation time and the elongational viscosity measured in the CaBER with the first normal stress difference and the relaxation time from the rheometer measurements. All these four quantities depend on different fluid parameters - the viscosity of the polymer solution, the polymer concentration within the solution, and the molecular weight of the polymers - and on the shear rate (in the shear flow measurements). Nevertheless, we found that the first normal stress coefficient depends quadratically on the CaBER relaxation time. A simple model is presented that explains this relation on a phenomenological level.