Regensburg 2010 – wissenschaftliches Programm

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SYMR: Symposium Nuclear Magnetic Resonance: from Applications in Condensed-Matter Physics to New Frontiers

SYMR 8: Glasses and Glass Transition

SYMR 8.7: Vortrag

Mittwoch, 24. März 2010, 16:15–16:30, H48

Glass Transition of Molecules Sorbed in ZeolitesÖzlen F. Erdem1, •Dieter Michel2, Pavel Sedykh2, and Jürgen Haase21Max-Planck-Institute of Bioinorganic Chemistry, Stiftstraße 34-36, 45470 Mülheim an der Ruhr, Germany — 2University of Leipzig, Faculty of Physics and Earth Sciences, Linnéstraße 5, 04103 Leipzig, Germany

Proton MAS NMR, nuclear spin relaxation, and deuteron NMR spectroscopy are combined to study the mobility of ethylene glycol molecules sorbed in various zeolites over a wide temperature range. The results obtained will be also compared with broad-band dielectric measurements and with previous extensive dielectric studies by Kremer et al. [1]. The main question is whether the adsorbed species show a so called single-molecule behavior characterized by an Arrhenius type temperature dependence of the correlation times or the respective dielectric relaxation times. In contrast, a Vogel-Fulcher-Tammann (VFT) type temperature dependence of the dielectric relaxation rate would point out collective motions and is typical for the appearance of a glass-transition. An important question is the competition between molecule-to-molecule and molecule-to-surface interactions.

[1] F. Kremer, A. Huwe, M. Arndt, P. Behrens, W. Schwieger, J. Phys. Cond. Mat. 11, A175-A188 (1999); A. Huwe, F. Kremer, J. Kärger, P. Behrens, W. Schwieger, G. Ihlein, O. Weiss, F. Schuth, J. Mol. Liquids 86, 173-182 (2000).

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