Dresden 2020 – wissenschaftliches Programm

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 96: Organic Electronics and Photovoltaics IV

CPP 96.9: Vortrag

Donnerstag, 19. März 2020, 17:15–17:30, ZEU 260

Numerical Modeling of Transient Electroluminescence based on Thermally Activated Delayed Fluorescence — •Jeannine Grüne, Nikolai Bunzmann, Sebastian Weißenseel, Vladimir Dyakonov, and Andreas Sperlich — Experimental Physics VI, Julius Maximilian University of Würzburg, 97074 Würzburg

Organic light emitting diodes (OLEDs) based on thermally activated delayed fluorescence (TADF) show increased efficiencies due to effective upconversion from the non-emissive triplet states to the emissive singlet state via reverse intersystem crossing (RISC). A promising approach in this field are donor:acceptor configurations, whereby an intermolecular exciton is formed at the interface of two molecules, also called exciplex. A proven material combination is among others 4,4’,4”-Tris[(3-methylphenyl)phenylamino]triphenylamine (m-MTDATA), as donor and Tris(2,4,6-trimethyl-3-(pyridin-3-yl)phenyl)borane (3TPYMB), as acceptor. The characterisitc behaviour especially in transient measurements differs from what is commonly observed in state of the art intramolecular emitters. In order to gain insight into the ongoing processes in exciplex based OLEDs, we performed numerical fits on transient electroluminescence (trEL) measurements at different temperatures. The kinetic model adapted for EL measurements on TADF systems includes second order terms to consider the existing annihilation processes such as triplet-triplet annihilation. Using this procedure, we can quantify the impact of efficiency-enhancing and efficiency-reducing processes as well as the time-dependent excited state populations.

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