Dresden 2020 – scientific programme
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O: Fachverband Oberflächenphysik
O 51: Poster Session - Metal Substrates: Adsorption and Reaction of Small Molecules
O 51.1: Poster
Tuesday, March 17, 2020, 18:15–20:00, P2/1OG
Electronic Structure of a Highly Ordered B3N3-Doped Nanographene Monolayer on Au(111) — •Axel Belser1, Katharina Greulich1, Holger F. Bettinger2, Heiko Peisert1, and Thomas Chassé1 — 1Institute of Physical and Theoretical Chemistry, University of Tuebingen — 2Institute of Organic Chemistry, University of Tuebingen
Electronic interface properties and the initial growth of hexa-peri-hexabenzocoronene with a borazine core (BN-HBC) on Au(111) have been studied by using X-ray photoelectron spectroscopy (XPS), scanning tunneling microscopy (STM) and low energy electron diffraction (LEED). The results are compared to hexa-peri-benzocoronene (HBC). Both molecules form well-defined monolayers, in particular after annealing of 2-3 monolayers to 300 ∘C. Valuable information about the electronic structure is obtained by a variation of the tunneling voltage. The distribution of the HOMO and the LUMO determined tentatively by STM is in good agreement to DFT calculations.