Regensburg 2022 – wissenschaftliches Programm
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CPP: Fachverband Chemische Physik und Polymerphysik
CPP 10: 2D Materials 2 (joint session HL/CPP/DS)
CPP 10.6: Vortrag
Montag, 5. September 2022, 16:30–16:45, H36
exciton species in highly doped WS2 monolayers — david tiede, •hossein ostovar, hendrik lambers, nihit saigal, and ursula wurstbauer — Institute of Physics, University of Münster, Münster, Germany
Semiconducting two-dimensional transition metal dichalcogenides such as WS2 excel due to their exciton dominated light-matter interaction even at room temperature (RT) that is highly tunable by external stimuli such as doping, light excitation, dielectric environment, or strain [1]. In this work, an optimized field effect structure utilizing a polymer electrolyte top gate electrode is employed to study the evolution of the optical response in monolayer WS2 at RT in dependence of doping by means of photoluminescence and spectroscopic imaging ellipsometry measurements. The huge geometrical gate capacitance enables capacitance spectroscopy of the conduction band as well as valence band edge yielding a gap energy of 2.6eV in agreement with the determination from the exciton Rydberg series. The gate allows the injection of large electron and hole densities exceeding 1014 cm−2, sufficient to enable the exciton Mott transition. The obtained doping dependent emission and absorption spectra also facilitate the identification of phonon activated, neutral and charged exciton species as well as dressed excitons in a fermi sea. We acknowledge financial support via DFG WU 637/7-1 and SPP2244. [1] U. Wurstbauer et al. J. Phys. D: Appl. Phys. 50, 173001 (2017).