Regensburg 2022 – wissenschaftliches Programm
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O: Fachverband Oberflächenphysik
O 70: Supported nanoclusters: Structure, Reactions, Catalysis
O 70.4: Vortrag
Donnerstag, 8. September 2022, 16:00–16:15, H6
Tuning SMSI Kinetics on Pt-loaded TiO2(110) by Choosing the Pressure — •Philip Petzoldt1, Moritz Eder1, Sonia Mackewicz1, Monika Blum2,3, Tim Kratky4, Sebastian Günther4, Martin Tschurl1, Ueli Heiz1, and Barbara Lechner5 — 1Physical Chemistry, Department of Chemistry and Catalysis Research Center, Technical University of Munich — 2Advanced Light Source, Lawrence Berkeley National Laboratory — 3Chemical Sciences Division, Lawrence Berkeley National Laboratory — 4Physical Chemistry with Focus on Catalysis, Department of Chemistry and Catalysis Research Center, Technical University of Munich — 5Functional Nanomaterials, Department of Chemistry and Catalysis Research Center, Technical University of Munich
The encapsulation of noble metal particles on reducible supports due to a strong metal-support interaction (SMSI) has already been extensively studied. However, there is still an ongoing debate on important aspects such as the influence of oxygen or hydrogen treatments on the encapsulating overlayer. We have utilized synchrotron-based NAP-XPS in order to investigate the SMSI for Pt-loaded TiO2(110) single crystals under the influence of H2 and O2 at different pressures. In an O2 atmosphere two different, pressure-dependent phenomena, namely, an oxidation of Pt particles and a loss of Pt signal intensity, are observed at 800 K. While the oxidation is partially reversed in vacuum, the intensity of the platinum signal cannot be recovered. H2 annealing has no significant additional effect compared to vacuum annealing. In the presentation, we discuss possible origins of these observations.