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Regensburg 2007 – wissenschaftliches Programm

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 11: INTERNAL SYMPOSIUM Scattering Experiments II

CPP 11.12: Vortrag

Dienstag, 27. März 2007, 18:00–18:15, H37

Polymer-based nanocomposites investigated with microGISAXS — •S.V. Roth1, A. Veligzhanin1, H. Walter2, R. Domnick3, O. Leupold1, R. Gehrke1, and P. Müller-Buschbaum41HASYLAB at DESY, Notkestr. 85, D-22607 Hamburg, Germany — 2CSEM SA, Badenerstrasse 569, CH-8048 Zürich, Switzerland — 3Ara-Coatings GmbH & Co. KG, Gundstr. 13, D-91056 Erlangen, Germany — 4TU München Physik Department LS E13, James-Franck-Str.1, D-85747 Garching, Germany

Polymer-based nanocomposites allow to combine the extraordinary features of the individual materials forming the nanocomposite. Especially the richness of polymer structures in blend as well as block-copolymer systems in thin film geometry gives rise to new classes of nanocomposite materials. Annealing as a second step in nanocomposite preparation allows for further nanostructuring the polymer film inducing e.g. a definite roughness or particle distribution. In our approach we combine the richness of the polymer structure with a metal coating [1,2]. Such polymer-based metal nanocomposites are widely used in many optical and biotechnological applications. As experimental method to study such nanocomposites, we used microbeam grazing incidence small-angle x-ray scattering at the beamline BW4 of HASYLAB (Hamburg). Our results reveal the dominating influence of the polymer layer in the structure of this nanocomposite.

[1] S.V. Roth et al., Appl. Phys. Lett. 82, 1935 (2003)

[2] S.V. Roth et al., Appl. Phys. Lett. 88, 021910 (2006)

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