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CPP: Fachverband Chemische Physik und Polymerphysik
CPP 49: Poster Session II
CPP 49.2: Poster
Dienstag, 17. März 2020, 14:00–16:00, P1A
Morphology Study of self-assembled Supramolecular Structures — •Asena Cerhan1, Christopher Greve1, Michael Buchhorn1, Richard Kellnberger1, Bernd Wittmann2, Felix Wenzel3, Hans-Werner Schmidt3, Richard Hildner2,4, and Eva M. Herzig1 — 1Dynamik und Strukturbildung - Herzig Group, Universität Bayreuth, Universitätsstr. 30, 95447 Bayreuth — 2Lehrstuhl für Spektroskopie weicher Materie, Universität Bayreuth, Universitätsstr. 30, 95447 Bayreuth — 3Makromolekulare Chemie I, Universität Bayreuth, Universitätsstr. 30, 95447 Bayreuth — 4Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4 9747 AG Groningen, Netherlands
Organic, supramolecular systems can exhibit extraordinary transport properties [1]. Here we investigate the self-assembly of a carbonyl-bridged triarylamine (CBT) small molecule into helical supramolecular nanostructures [2]. The self-assembly is sensitive to environmental parameters like solvent type and temperature. Using x-ray scattering on the system in various solvents we are able to study the morphology of supramolecular nanostructures formed from CBT molecules. Examining the morphology further with temperature resolved measurements, as well as comparisons of behaviour in solution versus thin films, allows us to learn more about the intermolecular interactions, that are key for their functional properties. [1] Brixner, T., Hildner, R., Köhler, J., Lambert, C. & Würthner, F. Adv. Energy Mater. 7, 1700236 (2017).[2] Haedler, A. T. et al. Nature 523, 196-199 (2015).