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Dresden 2020 – wissenschaftliches Programm

Die DPG-Frühjahrstagung in Dresden musste abgesagt werden! Lesen Sie mehr ...

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 90: Perovskite and photovoltaics V (joint session HL/CPP)

CPP 90.6: Vortrag

Donnerstag, 19. März 2020, 11:15–11:30, POT 251

Charge Carrier Transport in Halide Perovskites Investigated by Optical-Pump Terahertz-Probe SpectroscopyHannes Hempel1, •Andrei Petsiuk1, Martin Stolterfoht2, Pascal Becker1, Dieter Neher2, Rainer Eichberger1, and Thomas Unold11Helmholtz Zentrum Berlin für Materialien und Energie GmbH — 2Institute of Physics and Astronomy, Universität Potsdam

Metal-halide hybrid perovskites exhibit excellent optoelectronic properties except for their rather moderate charge carrier mobilities. The origin of these moderate mobilities has been attributed to several (contradicting) effects, such as the formation of large and small polarons, dynamic disorder due to the soft nature of these materials, slow rotational modes of the organic molecules, as well as to the confinement of charge carriers in grains, ferroelectric domains or nanostructures. To clarify the nature of the charge carrier transport, we probed different hybrid and inorganic halide perovskites thin films and nano-crystals by temperature dependent Optical-Pump Terahertz-Probe (OPTP) spectroscopy. We find a strongly increasing mobilities with lower temperature, thus excluding small polaron formation and hopping transport. Instead, this behavior can be modeled by conventional large polaron theory and Fröhlich-type electron-phonon scattering.

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