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Dresden 2020 – wissenschaftliches Programm

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HL: Fachverband Halbleiterphysik

HL 53: Hybrid Perovskite and Photovoltaics II (joint session CPP/HL)

HL 53.1: Vortrag

Mittwoch, 18. März 2020, 15:00–15:15, ZEU 260

The Efficiency Potential of Neat Perovskite Films — •Martin Stolterfoht — Uni Potsdam

Perovskite photovoltaic (PV) cells have demonstrated power conversion efficiencies (PCE) that are close to those of monocrystalline silicon (m-Si) cells, however, in contrast to silicon PV, perovskites are not limited by Auger recombination. Nevertheless, compared to GaAs and m-Si devices, perovskite cells stand out by their significantly lower fill factors (FFs) which is due to a combination of resistive and non-radiative recombination losses. This necessitates a deeper understanding of the underlying loss mechanism and in particular the ideality factor of the cell. Here, by measuring the intensity (I) dependence of the external (V_OC) and internal voltage (i.e. the quasi-Fermi level splitting, QFLS), we can quantify the transport resistance-free efficiency of the complete cell as well as the efficiency potential of any neat perovskite films with and without attached transport layers (TLs). Moreover, QFLS(I) measurements on different perovskite compositions allow to disentangle the impact of the interfaces and the perovskite surface on the non-radiative FF and V_OC loss. We find that potassium passivated quadruple cation perovskite films stand out by their exceptionally high implied PCEs of above 28% which could be readily achieved if charge collection losses and energy alignment issues are overcome. Finally, strategies are presented to reduce both the ideality factor and transport losses to push the FF to the thermodynamic limits.

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